Will a U/25mm hook be ideal for this yarn?

These are chunky yarn, it will be better knit without hook ,use hand is easier .

About how many skeins of this yarn for a baby’s blanket?

4 Skeins for a size of 30x40inch blanket

about how many spools would it take to make an average throw blanket?

As part of your pattern you should have a listing for number of skeins you will then need to find out weight per skein to make sure you are buying the correct amount. When I used this sight the amount per unit price was close to a skein. Some sites are not. Next would be size of blanket and tightness of your sitch. With the chenille yarn you get a nice single size lap thow or blanket out of 5 skeins using arm or hand knit method

Brand	FAU-Chunky Chenille Yarn
Model Number	dhy025
Color	Orange
Package Dimensions	24.21 x 22 x 3.99 cm; 226.8 g
Material	Polyester
Item Weight	226 g

FAU-Chunky Chenille Yarn Orange Super Chunky Jumbo Soft Arm Knitting Crocheted Blanket Giant Knit Blanket? ,Moms Present,250g

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