They do not float on the surface, but they have enough bouancy to require tiny split shot to carry them down to the desired depth for feeding fish. So the most adequate answer I have for the question of ‘do they float’ is...almost.

They're not plastic, they're like a gel or jelly substance.

Does it work for bass in river?

I’m sure this would act as a scent attractant for any species of fish.

No, not plastic. Seems to be something that melts away and leaves a scent trail.

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PFBLS-COHO Fire Balls

Product ID: 354204483

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Description

Specifications

Color	Chartreuse/Anise
Brand	PAUTZKE'S
Size	1.65 oz
Material	Biodegradable Eggs
Item Weight	0.21 Pounds
Item dimensions L x W x H	2 x 2 x 3 inches
Number of Pieces	1
Target Species	Trout, Salmon
Item Package Dimensions L x W x H	2.72 x 1.81 x 1.73 inches
Package Weight	0.16 Kilograms
Item Dimensions LxWxH	2 x 2 x 3 inches
Brand Name	PAUTZKE'S
Model Name	Pautzke Fire Balls
Suggested Users	unisex-adult
Number of Items	1
Manufacturer	Pautzke Bait Co.
Part Number	PFBLS-CHT-ANS-1.65OZ
Style	Fire Balls
Included Components	Fire Balls, Chartreuse/Anise, 1.65 OZ
Sport Type	Fishing
Fishing Technique	Fish Bait

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